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Beilstein J. Org. Chem. 2013, 9, 647–654, doi:10.3762/bjoc.9.73
Graphical Abstract
Figure 1: Molecular representations of N-heterocyclic carbenes and BMIM-2-CO2.
Scheme 1: Ring-opening polymerization of ε-caprolactone and rac-lactide by using BMIM-2-CO2 as precatalyst (1...
Scheme 2: Possible mechanism for the synthesis of PCL and PLA by ROP using BMIM-2-CO2 as precatalyst.
Scheme 3: In situ formation of monobenzylcarbonate and deactivation of N-heterocyclic carbene.